2024年最新杏吧视频官方网站

杏吧视频
成江 博士
教授,博士生导师
化学系
    • · 应用过渡金属催化的C-H键官能团化反应 · 自由基参与的有机合成方法学 · 二氧化碳的化学固定反应

个人简介

个人简介

成江,男,汉族,1974年11月出生,浙江省义乌市人,中共党员,教授,博士生导师、硕士生导师。1995年获得南京大学应用化学学士学位,2001年获得南京大学高分子化学与物理专利硕士学位,2001年至2004年和上海有机化学所联培,于2004年获得南京大学有机化学博士学位。主持4项国家自然科学基金面上项目、一项国家自然科学基金青年基金项目。2012年为洪堡学者(experienced researcher)在德国亚琛工业大学开展工作。应用过渡金属催化的C-H键官能团化反应、自由基参与的有机合成方法学以及二氧化碳的化学固定反应等,发展一些具有药理、生理活性的先导杂环化合物骨架的快捷、绿色的构建方法。自2005年独立开展科研工作以来,共发表SCI论文140余篇,被引6000余次,H因子为45。其中Angew. Chem., Int. Ed., 1篇, Chem. Commun. 28篇,Org. Lett. 22篇(以上51篇均为Nature Index收录期刊),Adv. Synth. Catal. 10篇,以及J. Org. Chem. 23篇。   

 

代表性论文

  1. Rhodium-Catalyzed   Reaction of Sulfoxonium Ylides and Anthranils toward Indoloindolones via a (4   + 1) Annulation. Wu, X.; Xiao, Y.; Sun, S.; Yu, J.-T.; Cheng, J.Org. Lett. 2019, 21, 6653. (IF 6.579)

         2. Visible-Light-Driven Palladium-Catalyzed   Oxy-Alkylation of 2-(1-Arylvinyl)anilines   by Unactivated Alkyl Bromides and CO2: Multicomponent Reactions toward 1,4-Dihydro-2H-3,1-benzoxazin-2-ones. Sun, S.; Zhou, C.; Yu, J.-T.; Cheng, J.Org. Lett. 2019, 21, 6579. (IF 6.579)

         3. The Reaction of o-Aminoacetophenone N-Tosylhydrazone and CO2 toward   1,4-Dihydro-2H-3,1-benzoxazin-2-ones. Xiong, H.; Wu, X.;   Wang, H.; Sun, S.; Yu, J.-T. Cheng, J.* Adv. Synth. Catal. 2019, 3613538.(IF 5.646).

         4. Rhodium-Catalyzed   Reaction of Azobenzenes and Nitrosoarenes toward Phenazines. Xiao, Y.; Wu, X.; Wang, H.; Sun, S.; Yu, J.-T.; Cheng, J.Org. Lett. 2019, 21, 2565. (IF 6.579).

         5. Palladium/copper-catalyzed multicomponent reactions of propargylic   amides, halohydrocarbons and CO2 toward functionalized oxazolidine-2,4-diones. Zhou C.; Dong Y.; Yu J.-T.; Sun S.*; Cheng, J.* Chem. Commun. 2019, DOI: 10.1039/c9cc07027c. (IF 6.319).

         6. The Silver-Promoted   Phosphonation/Alkynylation of Alkene Proceeding with Radical 1,2-Alkynyl   Migration. Jin, S.; Sun, S.; Yu, J.-T.; Cheng, J.* J. Org. Chem. 201984, 11177 (IF 4.785).

         7. Rhodium-Catalyzed Relay Carbenoid Functionalization of Aromatic C-H   Bonds toward Fused Heteroarenes, Wu, X.; Xiong, H .; Sun, S,; Cheng, J.* Org. Lett. 201820, 1396. (IF   6.579)

         8. Site-specific   hydroxyalkylation of chromones via alcohol mediated Minisci-type radical   conjugate addition, Chen, R.; Yu, J.-T.; Cheng, J.* Org. Biomol. Chem. 201816, 1823. (IF 3.564)

         9.  Radical rearrangement of N-sulfonyl-N-aryl propynamides:   proceeding with homolytic N-SO2 bond cleavage and 6-endo-dig cyclization   toward 3-sulfonyl-2(1H)-quinolinones, Wang, B.; Jin, S.; Sun, S.; Cheng, J.* Org. Chem. Front. 20185, 958 (IF 4.955).

         10.  Palladium-catalyzed CO-free cyclizative carbonylation of   2-benzylpyridines leading to pyridoisoquinolinones, Yang, R.; Yu, J.-T.; Sun,   S.; Cheng,   J.* Org. Chem. Front. 20185, 962 (IF 4.955).

         11.   Rh-Catalyzed   Annulation of ortho-C-H Bonds of 2-Arylimidazoles with 1,4,2-Dioxazol-5-ones   toward 5-Arylimidazo[1,2-c]quinazolines, Wu, X.; Sun, S.; Xu, S.; Cheng, J.* Adv. Synth. Catal. 2018360, 1111 (IF 5.646).

         12. Palladium-Catalyzed   Safe Cyanation of Aryl Iodides with Hexamethylenetetramine, Yan, Y.; Sun, S.;   Cheng, J.* J. Org. Chem. 201782, 12888 (IF 4.785).

         13.   Palladium-Catalyzed   [5+1] Annulation of 2-(1-Arylvinyl) Anilines and alpha-Diazocarbonyl   Compounds toward Multi-functionalized Quinolines, Zhu, J.; Hu, W.; Sun, S.;   Yu, J.-T.; Cheng, J.* Adv. Synth. Catal. 2017359, 3725 (IF 5.646)

         14.   The Base-Promoted   Annulation of 2-Hydrazinyl Pyridine and CO2 toward Triazolones, Wu, X.; Sun,   S.; Wang, B.; Cheng, J.* Adv.   Synth. Catal. 2017359, 3855 (IF 5.646)

         15.   Copper-Catalyzed   Arylsulfonylation and Cyclizative Carbonation of N-(Arylsulfonyl)acrylamides   Involving Desulfonative Arrangement toward Sulfonated Oxindoles, Wang, H.;   Sun, S.; Cheng, J.* Org. Lett. 201719, 5844. (IF 6.579)

         16.   Copper-catalyzed   radical 1,2-cyclization of indoles with arylsulfonyl hydrazides: access to   2-thiolated 3H-pyrrolo[1,2-a]indoles, Zhu, J.; Sun, S.; Xia, M.; Gu, N.; Cheng, J.* Org. Chem. Front. 20174, 2153 (IF 4.955).

         17.   Palladium-Catalyzed   Multicomponent Reactions of o-Alkynylanilines, Aryl Iodid.es, and CO2 toward   3,3-Diaryl 2,4-Quinolinediones, Wang, B.; Sun, S.; Yu, J.-T.; Jiang, Y.; Cheng, J.* Org. Lett. 201719, 4319. (IF   6.579)

          18.   Synthesis of   2-Amino-3-hydroxy-3H-indoles via Palladium-Catalyzed One-Pot Reaction of   Isonitriles, Oxygen, and N-Tosylhydrazones Derived from 2-Acylanilines, Chu,   H.; Dai, Q.; Jiang, Y.; Cheng, J.* J. Org. Chem. 201782, 8267. (IF 4.785)

          19.   1,2-Arylalkylation of   N-(arylsulfonyl)acrylamides using aliphatic aldehydes as the alkyl source,   Yu, J.-T.; Chen, R.; Zhu, J.; Cheng, J.* Org. Biomol. Chem. 201715, 5476. (IF   3.564)

          20.   Rh(III)-catalyzed   bilateral cyclization of aldehydes with nitrosos toward unsymmetrical   acridines proceeding with C-H functionalization enabled by transient   directing group, Hu,W., Zheng, Q.; Sun, S.; Cheng, J.* Chem. Commun. 201753, 6263 (IF 6.319).

          21.   The dearomative   annulation between N-2-pyridylamidine and CO2 toward   pyrido[1,2-a]-1,3,5-triazin-4-ones, Xia, M.; Hu, W.; Sun, S.; Yu, J.-T.;  Cheng, J.* Org. Biomol. Chem. 201715, 4064. (IF 3.564)

          22.   Aqueous MCRs of quaternary ammoniums, N-substituted formamides and sodium disulfide towards aryl thioamides, Zhou, Z.; Yu,   J.-T.; Zhou, Y.; Jiang, Y.; Cheng, J.Org. Chem. Front. 20174, 413 (IF 4.955).

          23.   Carbon annulation of ortho-vinylanilines with dimethyl sulfoxide to   access 4-aryl quinolines, Yuan J.; Yu J.-T.; Jiang Y.; Cheng, J.* Org. Biomol. Chem. 201715, 1334 (IF 3.564).

          24.   Copper-mediated annulation of 2-(1-arylvinyl) anilines and aryl nitrosos   towards 2,3-diaryl-2H-indazoles, Hu, W.; Yu,   J.-T.; Liu, S.; Jiang, Y.; Cheng, J.* Org. Chem.   Front. 20174, 22 (IF 4.955).

          25.   Palladium-Catalyzed Arylcarboxylation of Propargylic Alcohols with CO2   and Aryl Halides: Access to Functionalized α-Alkylidene Cyclic Carbonates, Sun S.;   Wang B.; Gu N.; Yu J.-T.; Cheng, J.* Org. Lett. 201719, 1088 (IF 6.579).

          26.     The   Construction of X-CN (X=N, S, O) Bonds, Yu,   J.-T.; Teng, F.; Cheng, J.* Adv. Synth. Catal. 2017359, 26 (IF 6.5.646).

          27.   Multicomponent Coupling Reactions of Two N-Tosyl Hydrazones and   Elemental Sulfur: Selective Denitrogenation Pathway toward Unsymmetric 2,5-Disubstituted 1,3,4-Thiadiazoles,  Zhou Z.; Liu Y.; Chen J.; Yao E.; Cheng, J.* Org. Lett. 201618, 5268 (IF 6.579).

          28.   Copper-catalyzed   N-thioetherification of sulfoximines using disulfides, Zhu, H.; Yu, J.-T. * ; Cheng, J. * Chem. Commun. 201652, 11098 (IF 6.319).

          29.  Iron-Mediated Annulation between Methylene Ketones and Diethan-olamines: a Sustainable and Scalable Procedure towards N-(2-Hydroxyethyl) Pyrroles, Hu, W.; Yu, J.-T.; Ye, D.; Zhou Z.; Sun, S.; Cheng, J.* J. Org. Chem. 201681, 9389 (IF 4.849).

          30.  Rhodium-Catalyzed Annulation of Primary Benzylamine with α-Diazo Ketone toward Isoquinoline, Chu, H.; Xue, P.; Yu, J.-T.; Cheng, J.* J. Org. Chem. 201681, 8009 (IF 4.849).

          31.  Formal [3+2] Reaction of α,α-Diaryl Allylic Alcohols with sec-Alcohols: Proceeding with Sequential Radical Addition/Migration toward 2,3-Dihydrofurans Bearing Quaternary Carbon Centers, Hu, W.; Sun, S.; Cheng, J.* J. Org. Chem. 201681, 4399 (IF 4.849).

          32.  TBAI-Catalyzed Reaction between N-Tosylhydrazones and Sulfur: A Procedure toward 1,2,3-Thiadiazole, Chen, J.; Jiang, Y.; Yu, J.-T.; Cheng, J.* J. Org. Chem. 201681, 271 (IF 4.849).

          33.  Palladium-catalyzed three-component reaction of N-tosyl hydrazones, isonitriles and amines leading to amidines, Dai, Q.; Jiang, Y.; Yu, J.-T.; Cheng, J.* Chem. Commun. 201551, 16645 (IF 6.319).

          34.   The 3-Aza π-Allyl Palladium Derived from Imino Migratory in Palladium-Carbene: an MCRs Reaction Toward Multiple Substituted Indole Skeleton, Dai, Q.; Jiang, Y.; Guo, S.; Yu, J.-T.; Cheng, J.* Chem. Commun. 201551, 14781 (IF 6.319).

          35.  Diethylene Glycol Serving as Ethyne Equivalent: A Sustainable Approach toward 2,3-Disubstituted Furan, Yu, J.-T.; Shi, B.; Peng, H.; Sun, S.; Chu, H.; Jiang, Y.; Cheng, J.* Org. Lett. 201517, 3643 (IF 6.579).

          36.  Rh-catalyzed sequential oxidative C−H activation/annulation with geminal-substituted vinyl acetates to access isoquinolines, Chu, H.; Sun, S.; Yu, J.-T.;* Cheng, J.* Chem. Commun. 201551, 13327 (IF 6.319).

          37.  Silver-Mediated N-Trifluoromethylation of Sulfoximines, Teng, F.; Cheng, J.;*Bolm, C.* Org. Lett. 201517, 3166 (IF 6.579).

          38.  Copper(I)-catalyzed desulfinative carboxylation of sodium sulfinates using carbon dioxide, Sun, S.; Yu, J.-T.; Cheng, J.* Adv. Synth. Catal2015357, 2022 (IF 6.453).

          39.  Cs2CO3-Promoted Carboxylation of N-Tosylhydrazones with Carbon Dioxide towards α-Arylacrylic Acids, Sun, S.; Yu, J.-T.; Jiang, Y.; Cheng, J.* J. Org. Chem. 201580, 2855 (IF 4.849).

          40.  Copper-catalyzed oxidative C(sp3)-H/N-H coupling of sulfoximines, amides with simple alkanes via radical process, Teng, F.; Sun, S.; Jiang, Y.; Yu, J.-T.;* Cheng, J.* Chem. Commun. 201551, 5902 (IF 6.319).

          41.  Iodine-catalyzed ammoxidation of methyl arenes, Guo, S.; Wan, G.; Sun, S.; Jiang, Y.; Yu, J.-T.; Cheng, J.* Chem. Commun201551, 5085 (IF 6.319).

          42.  Copper-Catalyzed N-Cyanation of Sulfoximines by AIBN, Teng, F.; Yu, J.-T.; Zhou, Z.; Chu, H.; Cheng, J.* J. Org.Chem201580, 2822 (IF 4.849).

          43.  Di-tert-butyl Peroxide-Promoted α-Alkylation of α-Amino Carbonyl Compounds by Simple Alkanes, Peng, H.; Yu, J.-T.; Jiang, Y.; Yang, H.; Cheng, J.* J. Org. Chem201479, 9847 (IF 4.849).

          44.  TBHP-promoted sequential radical silylation and aromatisation of aryl isonitriles with silanes, Wang, L.; Zhu, H.; Guo, G.; Cheng, J.* Yu, J.-T.* Chem. Commun. 201450, 10864 (IF 6.319).

          45.  Copper-Catalyzed Cyanation of Disulfides by Azobisisobutyronitrile Leading to Thiocyanates, Teng, F.; Yu, J.-T.; Yang, H.; Jiang, Y.; Cheng, J.* Chem. Coummun. 201450, 12139 (IF 6.319).

          46.  Di-tert Butyl Peroxide-Promoted Sequential Methylation and Intramolecular Aromatization of Isonitriles, Dai, Q.; Yu, J.-T.; Feng, X.; Jiang, Y.; Yang, H.; Cheng, J.* Adv. Synth. Catal.2014356, 3341 (IF 5.646).

          47.  The Benzoyl Peroxide-Promoted Functionalization of Simple Alkane with 2-Aryl Phenyl Isonitrile, Sha, W.; Yu, J.-T.; Jiang, Y.; Yang, H.; Cheng, J.* Chem. Commun201450, 9179 (IF 6.319).

          48.  The Copper-Mediated Oxidative N-Cyanation Reaction, Teng, F.; Yu, J.-T.; Y Jiang, Y.; Yang, H.; Cheng, J.*Chem. Commun. 201450, 8412 (IF 6.319).

          49.  The Benzoyl Peroxide Promoted Dual C-C Bond   Formation via Dual C-H Bond Cleavage: α- Phenanthridinylation of Ether by Isocyanide, Wang, L.; Sha, W.; Dai, Q.; Feng, X.; Wu, W.; Peng, P.; Chen, B.; Cheng, J.* Org. Lett. 201416, 2088 (IF 6.579).

          50.  The Bu4NI-catalyzed alfa-acyloxylation of ketones with benzylic alcohols, Guo, S.; Yu, J.-T.; Dai, Q.; Yang, H.; Cheng, J.* Chem. Commun201450, 6240 (IF 6.319).

          51.  The carbomethylation of arylacrylamides leading to 3-ethyl-3-substituted indolin-2-one by cascade radical addition/cyclization, Dai, Q.; Yu, J.; Jiang, Y.; Guo, S.; Yang, H.; Cheng, J.* Chem. Commun201450, 3865 (IF 6.319).

          52.  Copper-Mediated C3-Cyanation of Indole by the Combination of Amine and Ammonium, Liu, B.; Wang, J.; Zhang, B.; Sun, Y.; Wang, L.; Chen, J.; Cheng, J.* Chem. Commun201450, 2315 (IF 6.319).

         53.  The Base-Promoted Formal Arylation of Benzo[d]oxazoles with Acyl Chloride, Wang, L.; Ren, X.; Yu, J.; Jiang, Y.; Cheng, J.* J. Org. Chem201378, 12076 (IF 4.849).

          54.  Annulation of Alkynes with Aryl Ketal Hydrazones: Proceeding through C-H Activation and In Situ Directing Group Removal Leading to Indenones, Chen, S.; Yu, J.; Jiang, Y.; Chen, F.; Cheng, J.*Org. Lett201315, 4754 (IF 6.579).

          55.  Palladium-Catalyzed Cyanation of Aryl Halides with CuSCN, Zhang, G.; Yu, J.-T.; Hu, M.; Cheng, J.* J. Org. Chem201378, 2710 (IF 4.849).

          56.  The Copper-Catalyzed C3-Formylation of Indole C-H Bonds Using Tertiary Amines and Molecular Oxygen, Chen, J.; Liu, B.; Liu, D.; Cheng, J.* Adv. Synth. Catal. 2012, 354, 2438 (IF 5.646).

          57.  The palladium-catalyzed desulfitative cyanation of arenesulfonyl chlorides and sodium sulfinates. Chen, J.; Sun, Y.; Liu, B.; Liu, D.; Cheng, J.* Chem. Commun., 201248, 449 (IF 6.319).

          58.    Copper-Mediated Cyanation of Aryl Halide with the Combined Cyanide Source. Zhang, G.; Ren, X.; Chen, J.; Hu M.; and Cheng, J.* Org. Lett. 201113, 5004 (IF 6.579).

          59.    Palladium-Catalyzed Desulfitative C-Arylation of Benzo[d]oxazole C-H Bond with Arenesulfonyl Chlorides. Zhang, M.; Zhang, S.; Cheng, J.* Chem. Commun201147, 11522 (IF 6.319).

          60.  The palladium-catalyzed cyanation of indole C–H bonds with the combination of NH4HCO3 and   DMSO as a safe cyanide source. Ren, X.; Chen, J.; Chen, F.;* Cheng, J.* Chem. Commun201147, 6725 (IF 6.319).

          61.  Rhodium or Palladium-Catalyzed Cascade Aryl Addition/Intramolecular Lactonization of Phthalaldehyde with Potassium Organotrifluoroborates to Access 3-Arylphthalides. Luo, F.; Pan,S.; Pan,C.; Qian, P.; Cheng, J.* Adv. Synth. Catal. 2011353, 320 (IF 5.646).

          62.  Copper(I)-Mediated Cyanation of Boronic Acids. Zhang, G.; Zhang, L.; Hu, M.*; Cheng, J.* Adv. Synth. Catal. 2011353, 291 (IF 5.646).

          63.  Copper(II)-Catalyzed Ortho-Functionalization of 2-Arylpyridines with Acyl Chlorides. Wang, W.; Pan, C.; Chen, F.*; Cheng, J.* Chem. Commun. 201147, 3978 (IF 6.319).

          64.  Copper-Mediated Methylthiolation of Aryl Halides with DMSO. Luo, F.; Pan,C.; Li, l.; Chen, F.*; Cheng, J.* Chem. Commun. 2011, 5304 (IF 6.319).

          65.  Rhodium-Catalyzed Cascade Reaction: Aryl Addition/Intramolecular Esterification to Access 3-Aryl and 3-Alkenyl Phthalides. Ye, Z.; Lv, G.; Wang, W.; Zhang, M.; Cheng, J.* Angew. Chem. Int. Ed. 201049, 3607 (IF 11.709).

          66.  Cu(OTf)2-Mediated Chan-Lam Reaction of Carboxylic Acids to Access Phenolic Esters. Zhang, L.; Zhang G.; Zhang, M.; Cheng, J.* J. Org. Chem. 201075, 7472 (IF 4.849).

          67.    Palladium-Catalyzed Cascade Aryl Addition/Intramolecular Esterification Reaction of Phthalaldehyde to Access 3-Aryl and Alkenyl Phthalides. Ye, Z.; Qian, P.; Lv, G.; Luo, F.; Cheng, J.* J. Org. Chem. 201075, 6043 (IF 4.849).          

          68.  Copper-Catalyzed Sequential Alkyl/Aryl or Vinyl Esterification of Dicarboxylic Acid Anhydrides with Trialkoxysilanes. Luo, F.; Pan, C.; Qian, P.; Cheng, J.J. Org. Chem. 201075, 5379 (IF 4.849).

          69.  Copper(II)-Catalyzed Ortho-Acyloxylation of the 2-Arylpyridines sp2 C−H Bonds with Anhydrides, Using O2 as Terminal Oxidant. Wang, W.; Luo, F.; Zhang, S.; Cheng, J.J. Org. Chem. 201075, 2415 (IF 4.849).

          70.  Copper-Catalyzed Thiolation of the Di- or Trimethoxybenzene Arene C-H Bond with Disulfides. Zhang, S.; Qian, P.; Zhang, M.; Hu, M.; Cheng, J.* J. Org. Chem. 201075, 6732 (IF 4.849).

          71.  Palladium-Catalyzed Acylation of sp2 C-H bond: Direct Access to Ketones from Aldehydes. Jia, X.; Zhang, S.; Wang, W.; Luo, F.; Cheng, J.* Org. Lett. 200911, 3120 (IF 6.579).

          72.  Rhodium-Catalyzed ortho-Benzoxylation of sp2 C-H Bond. Ye, Z. Wang, W.; Luo, F.; Zhang, S.; Cheng, J.* Org. Lett. 200911, 3974 (IF 6.579).

          73.    Chelation-Assisted Palladium-Catalyzed Direct Cyanation of 2-Arylpyridine C-H Bonds. Jia, X.; Yang, D.; Zhang, S.; Cheng, J.Org. Lett. 200911, 4716 (IF 6.579).

          74.    Palladium-Catalyzed Aromatic Esterification of Aldehydes with Organoboronic Acids and Molecular Oxygen. Qin, C.; Wu,* H.; Chen, J.; Liu, M.; Cheng, J.;* Su, W.; Ding, J.; Org. Lett. 200810, 1537 (IF 6.579).

          75.  The Palladium-Catalyzed Addition of Aryl- and Heteroarylboronic Acids to Aldehydes. Qin, C.; Wu, H.;* Cheng, J.;* Chen, J.; Liu, M.; Zhang, W.; Su, W.; Ding, J. J. Org. Chem. 200772, 4102 (IF 4.849).

          76.  The Use of Calcium Carbide in One-pot Synthesis of Symmetric Diaryl Ethynes. Zhang, W.; Wu, H.; Liu, Z.; Zhong, P.; Zhang, L.; Huang, X.; Cheng, J.* Chem. Commun2006, 4826 (IF 6.319).

 

主要项目

共主持国家自然科学基金面上项目4项,青年基金项目1项。省基金杰出青年基金1项,省基金面上项目2项。

 1. 国家自然科学基金面上项目:二氧化碳作为C1来源在合成杂环化合物中的应用(No.   21971025),2020.01-2023.12,直接经费65万元,在研

 2. 国家自然科学基金面上项目:基于原位形成卡宾对烯基钯插入、迁移形的π烯丙基钯中间体的分子内环化反应研究(No. 21572025),2016.01-2019.12,直接经费65万元,在研;

 3. 江苏省高校自然科学研究重大项目:简单烷烃的自由基官能团化研究(No. 15KJA150001),2014.07-2017.06,经费30万元,在研;

 4. 江苏省自然科学基金面上项目:甲烷的官能团化研究(No. BK20171193), 2017.08-2019.07,经费10万元,在研;

 5. 江苏省高层次创新创业人才引进计划,2013.01-2016.12,省助经费100万元,已结题;

 6. 国家自然科学基金面上项目:过渡金属催化吸电子定位基团促进的苯环C-H 键官能团化(No.   22172028),2013.01-2016.12,经费80万元,已结题;

 7. 国家自然科学基金面上项目:过渡金属催化卤代芳烃对芳醛的Barbier类型反应研究(No. 20972115),2009.01-2011.12,经费34万元,已结题;

 8. 浙江省自然科学基金杰出青年科学基金项目:过渡金属催化C-H键对C-杂不饱和键的加成反应研究(No. R4110294),2011.03-2013.12,经费20万元,已结题;

 9. 教育部科技重点项目:过渡金属催化通过C-H键活化的腈化以及膦化反应(No. 209054),2009.01-2010.12,经费10万元,已结题;

 10. 国家自然科学基金青年项目:过渡金属催化共轭高聚物光电材料的合成、修饰以及表征(No. 20504023),2006.01-2008.12,经费26万元,已结题;

 11. 浙江省自然科学基金面上项目 富电子大位阻有机膦配体的合成及在C-CC-杂键形成中的应用(No.   Y404039),2006.3-2006.10,经费5万元,已结题;

 

 

获奖项目

1. 常州市优秀科技论文三等奖,铜催化以偶氮二异丁腈为氰源过硫化物的氰化反应合成硫氰酸酯,第一完成人,2015年;

2. 浙江省科学进步奖三等奖,绿色化学技术及金属试剂在有机合成中的应用研究,第二完成人,2009年;

3. 浙江省教育厅高校科研成果奖一等奖,有机锆、有机膦等金属和元素有机化合物的合成与应用,第三完成人,2005年;

4. 温州市人民政府科技进步奖三等奖,有机锆、有机膦等金属和元素有机化合物的合成与应用,第三完成人,2005年。

所获人才项目及荣誉称号

1. 江苏省333高层次人才培养计划 第三层次,2016年;

2. 江苏省高层次创新创业人才引进计划 事业单位创新人才,2013年;

3. 江苏省高校青蓝工程中青年学术带头人,2012年;

4. 德国洪堡学者,资深研究员 2011年;

5. 浙江省自然科学基金杰出青年基金获得者 2010年;

6. 温州市科技特派员,2009年;

7浙江省高等院校中青年学科带头人,2007年;

8浙江省151人才第三层次,2006年;

9温州市551人才第二层次,2006年。

指导学生获奖情况

1. 2018年江苏省优秀硕士学位论文,过渡金属催化含氮杂环化合物合成反应研究

2. 江苏省优秀本科毕业论文三等奖,自由基环化菲啶硅烷合成反应研究,2016年;

3. 江苏省优秀本科毕业论文二等奖,基于单质硫的C-S键形成反应研究,2015年;

4. 浙江省第十一届挑战杯动感地带大学生课外学术科技作品竞赛二等奖Rh/Cu/TBAF催化的芳基硅烷对炔烃的加成反应;

5. 浙江省研究生创新基金,过渡金属催化芳烃C—H键对碳杂不饱和键加成反应(Yk2008093);

6. 浙江省新苗计划,过渡金属催化通过C-H活化合成咔唑衍生物;

7. 浙江省大学生科技创新创业孵化项目,铜催化的苯硼酸的三氟甲基化(2010R424064);

8. 浙江省大学生科技科技成果推广项目,铜催化的芳基硼酸与羧酸生成芳酯的反应研究(2010R424058)。

9. 2010年度浙江省优秀硕士论文,铑催化的C-H键活化及钯催化的偶联反应研究

10. 2009年度浙江省优秀硕士论文,过渡金属催化钯、铜催化的偶联反应研究