2024年最新杏吧视频官方网站

 个人简介

  汤浩，博士，教授。主要从事理论计算化学研究，研究领域包括计算无机电催化、有机过渡金属催化、仿生酶催化机理。近年来已用量子化学计算，探究无机催化剂表面电子结构和反应活性联系，模拟电催化原子动态，揭示反应路径，助力设计高活性、稳定的无机电催化剂，推动燃料电池、电解水制氢等技术发展；围绕有机过渡金属催化剂的设计、活性调控及反应机理，用高精度计算，理解金属与配体协同的催化循环，分析反应中间体，优化催化选择性与活性，为药物、材料合成提供高效绿色路线；从仿生视角，用计算化学模拟酶活性中心与催化过程，对比天然酶和人工体系，开发仿生催化剂，为绿色合成、生物传感等领域开辟新径。目前已在国际学术期刊发表SCI论文多篇，其中以第一作者或者通讯身份发表学术论文20篇，ESI高被引论文1篇，包括J. Am. Chem. Soc.、ACS Catalysis、Inorganic Chemistry、J. Org. Chem.、Dalton Transactions、Physical Chemistry Chemical Physics、Journal of Computational Chemistry等。曾参加了多次美国化学会年会和美国高登学术会议等国际学术会议并做了相关工作报告，与国际氢化酶领域顶级实验课题组有深厚的合作基础。

  入选温州市“瓯越海智计划” 青年人才项目，荣获2024年浙江省第四届教师教学创新大赛一等奖、2024年温州大学第四届教师教学创新大赛一等奖、2024年温州大学青年教师教学竞赛一等奖、2022年温州大学第二届教师教学创新大赛课程思政微课专项赛二等奖、2021年温州大学教师课堂教学竞赛一等奖、温州大学“优秀教师”荣誉称号和杏吧视频 “华峰院长奖”。

教育及工作经历

2021.04 ― 至今 教授，温州大学，杏吧视频

2014.09 ― 2021.03 博士后，美国Texas A&M University 化学系，合作导师：Michael B. Hall

2013.03 ― 2014.06 中国科学院化学所，光化学实验室，姚建年院士、陈辉研究员课题组联合培养

2009.09 ― 2014.06 博士，吉林大学理论化学研究所、理论化学计算国家重点实验室硕博连读 ，导师：孙家钟院士、黄旭日教授

2005.09 ― 2009.07 理学学士，辽宁师范大学，化学化工学院

科研项目

1.国家自然科学基金（22303062），30万元，主持，在研；

2.浙江省自然科学基金（LQ22B030004），10万元，主持，已结题；

3.温州市科技计划（G20220023），10万元，主持，已结题。

研究成果

1. Yi-Bo Wang, Wei Liu, Ting Li, Yazhu Lu, Yi-Tian Yu, Hai-Tao Liu, Meiwen Liu, Pengfei Li,Peng-Cheng Qian,* Hao Tang,* Jia Guan, Long-Wu Ye, and Long Li.Gold/HNTf2-Cocatalyzed Asymmetric Annulation of Diazo-Alkynes: Divergent Construction of Atropisomeric Biaryls and Arylquinones.J. Am. Chem. Soc.2024, 146, 33804−33816. //doi.org/10.1021/jacs.4c12063.

2. Xuelian Li, Yingke Wang, Cheng Xu, Zeyi Guo, Yazhu Lu, Deqing Kong, Junfei Wang, Jia Guan,* Hao Tang*. Comparative Electrocatalysis of Hydrogen Production and Oxidation: Technetium versus Rhenium Tris(thiolate) Complexes. ChemCatChem, 2024, 0, e202400830. //doi.org/10.1002/cctc.202400830.  

3. Yafei Gao, Xuelian Li, Jeremiah E. Stevens, Hao Tang,* and Jeremy M. Smith*. Catalytic 1,3-Proton Transfer in Alkenes Enabled by Fe=NR Bond Cooperativity: A Strategy for pKa-Dictated Regioselective Transposition of C=C Double Bonds. J. Am. Chem. Soc. 2023, 145, 11978−11987. //doi.org/10.1021/jacs.2c13350.

4. Hao Tang, Xuelian Li, Zeyi Guo, Deqing Kong, Junfei Wang, Yazhu Lu, Yingke Wang, Cheng Xu, Luyi Zhu, and Jia Guan*. Metal-Stabilized Thiyl Radicals Design Inspired by Elemental Periodic Extension Notion for Ligand-Based Alkene Addition. Chemistry−A European Journal. 2023, 29, e202300552. //doi.org/10.1002/chem.202300552.

5. Jia Guan, Zeyi Guo, Xuelian Li, Hao Tang*. Theoretical Understanding of Reactions of Rhenium and Ruthenium Tris(thiolate) Complexes with Unsaturated Hydrocarbons: Noninnocent Nature of the Ligand, Mechanism, and Origin of Differential Reactivity. Inorg. Chem. 2023, 62, 2548−2560. //doi.org/10.1021/acs.inorgchem.2c02837.

6. Sam Yruegas, Hao Tang, Gayle Z. Bornovski, Xiaojun Su, Siyoung Sung, Michael B. Hall,* Michael Nippe,* Caleb D. Martin.* Nickel−Borolide Complexes and Their Complex Electronic Structure. Inorganic Chemistry, 2021, 60, 16160–16167. //doi.org/10.1021/acs.inorgchem.1c01845.

7. Hao Tang, Tyler M. Porter, Clifford P. Kubiak, Michael B. Hall.* Full Conformational Analyses of the Ultrafast Isomerization in Penta-coordinated Ru(S2C2(CF3)2)(CO)(PPh3)2: One Compound, Two Crystal Structures, Three CO Frequencies, 24 Stereoisomers, and 48 Transition States. Inorganic Chemistry, 2020, 59, 11757–11769.

8. Hao Tang, Edward N. Brothers, Craig A. Grapperhaus,* Michael B Hall.* Electrocatalytic Hydrogen Evolution and Oxidation with Rhenium Tris(thiolate) Complexes: A Competition between Rhenium and Sulfur for Electrons and Protons. ACS Catalysis, 2020, 10, 3778–3789. DOI: 10.1021/acscatal.9b04579.

9. Deborah Brazzolotto,† Lianke Wang,† Hao Tang,† Marcello Gennari, Nicolas Queyriaux, Christian Philouze, Serhiy Demeshko, Franc Meyer, Maylis Orio, Vincent Artero,* Michael B. Hall,* Carole Duboc.* Tuning Reactivity of Bioinspired [NiFe]-Hydrogenase Models by Ligand Design and Modeling the CO Inhibition Process. ACS Catalysis, 2018, 8, 10658–10667. DOI: 10.1021/acscatal.8b02830. (†共同一作)

10. Hao Tang, Michael B Hall.* Biomimetics of [NiFe]-Hydrogenase: Nickel- or Iron-Centered Proton Reduction Catalysis? J. Am. Chem. Soc., 2017, 139, 18065–18070. DOI: 10.1021/jacs.7b10425.

11. Hao Tang, Edward N. Brothers, Michael B Hall.* The Distinctive Electronic Structures of Rhenium Tris(thiolate) Complexes, an Unexpected Contrast to the Valence Isoelectronic Ruthenium Tris(thiolate) Complexes. Inorganic Chemistry, 2017, 56, 583–593. DOI: 10.1021/acs.inorgchem.6b02434.

12. Yihua Sun, Hao Tang, Kejuan Chen, Lianrui Hu, Jiannian Yao, Sason Shaik, Hui Chen.* Two-State Reactivity in low-Valent Iron-Mediated C-H Activation and the Implications for Other First-Row Transition Metals. J. Am. Chem. Soc., 2016, 138, 3715–3730. DOI: 10.1021/jacs.5b12150.

13. Hao Tang, Jia Guan, Michael B Hall.* Understanding the Radical Nature of an Oxidized Ruthenium Tris(thiolate) Complex and Its Role in the Chemistry. J. Am. Chem. Soc., 2015, 137, 15616–15619. DOI: 10.1021/jacs.5b09309. (ESI高被引论文)

14. Hao Tang, Xuri Huang,* Jiannian Yao, Hui Chen.* Understanding the Effects of Bidentate Directing Groups: A Unified Rationale for sp2 and sp3 C-H Bond Activations. J. Org. Chem., 2015, 80, 4672–4682. DOI: 10.1021/acs.joc.5b00580.

15. Hao Tang, Bingwei Zhou, Xuri Huang,* Congyang Wang,* Jiannian Yao, Hui Chen.* Origins of Selective C(sp2)-H Activation Using Transition Metal Complexes with N,N-Bidentate Directing Groups: A Combined Theoretical-Experimental Study. ACS Catalysis, 2014, 4, 649–656. DOI: 10.1021/cs401141k.

16. Yanwei Sun, Haiyang Jiang, Hao Tang, Haixia Xu, Huiling Liu,* Kai Sun, Xuri Huang. Theoretical Investigation on the Mechanism of FeCl3 Catalyzed Cross-Coupling Reaction of Alcohols with Alkenes. Molecular Physics, 2014, 112, 2107–2113. DOI: 10.1080/00268976.2014.886738.

17. Lili Zhang, Huiling Liu, Hao Tang, Xuri Huang. Theoretical investigation on the reaction of HS+ with CH3NH2. Chemical Papers, 2014, 68, 145–152. DOI: 10.2478/s11696-013-0412-y.

18. Hao Tang, Jia Guan, Huiling Liu,* Xuri Huang.* Comparative Insight into Electronic Properties and Reactivities toward C−H Bond Activation by Iron(IV)−Nitrido, Iron(IV)−Oxo, and Iron(IV)−Sulfido Complexes: A Theoretical Investigation. Inorganic Chemistry, 2013, 52, 2684–1696. DOI: 10.1021/ic302766f.

19. Hao Tang, Jia Guan, Huiling Liu,* Xuri Huang.* Analysis of an alternative to the H-atom abstraction mechanism in methane C−H bond activation by nonheme iron(IV)–oxo oxidants. Dalton Transactions, 2013, 42, 10260–10270. DOI: 10.1039/C3DT50866H.

20. Hao Tang, Zhuo Li, Yuhong Yang, Ying Zhao, Suqin Wan, Huiling Liu,* Xuri Huang.* Comparison of the FeO2+ and FeS2+ Complexes in the Cyanide and Isocyanide Ligand Environment for Methane Hydroxylation. Journal of Computational Chemistry, 2012, 33, 1448–1457. DOI: 10.1002/jcc.22978.

21. Hao Tang, Jia Guan, Lili Zhang, Huiling Liu,* Xuri Huang.*, The effect of the axial ligand on distinct reaction tunneling for methane hydroxylation by nonheme iron(IV)-oxo complexes. Physical Chemistry Chemical Physics, 2012, 14, 12863–12874. DOI: 10.1039/C2CP42423A.

22. Hongbo Xu, Huiling Liu, Jianchao Song, Yan Li, Yuhong Yang, Hao Tang, Xuri Huang. Theoretical Study on the Reaction of PH+ with H2O. Computational and Theoretical Chemistry, 2011, 966, 328–333. DOI: 10.1016/j.comptc.2011.03.031.

鼓励学生积极参加各类学科竞赛和科研活动，指导学生获得了多项国家级、省级及校级创新与创业项目立项。

招生专业：化学、材料科学与工程、资源与环境、材料与化工。

欢迎化学、材料、化工、物理、数学、计算机专业同学加入！在这里，每位同学都将享受导师一对一的悉心指导。导师会深度挖掘你的专业背景，精准把握你的兴趣点，为你量身定制专属研究课题。从前沿的学术探索，到实际的计算操作，你将在浓厚的学术氛围中，充分施展才华，收获知识与成长，实现科研梦想！

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