个人简介
邵黎雄,男,理学博士,教授,硕士生导师。2001年毕业于浙江大学化学系,获理学学士学位。同年免试推荐至中国科学院上海有机化学研究所硕-博连读,并于2006年7月获得理学博士学位。2006年7月进入华东理工大学化学与分子工程学院参加工作。2008年1月调入温州大学。目前主要从事新颖多芳基多羧酸配体的合成,及在功能性MOF合成中的应用研究。近年来,在Accounts of Chemical Research, Chemical Reviews, Organic Letters, The Journal of Organic Chemistry等SCI核心期刊上发表论文五十余篇。
代表论著
50. Guo, Qing-Cui; Xu, Ke-Yan; Bo, Xiao-Xu*; Lu, Jian-Mei*; Shao, Li-Xiong* Highly stable two-dimensional Cd-MOFs for selective detection of nitrofuran antibiotics. J. Mol. Strucct. 2026, 1352, 144621.
49. Zhang, Jian; Wang, Hai-Lan; Lu, Jian-Mei*; Shao, Li-Xiong* Construction of two-dimensional zinc-organic frameworks and application in the synthesis of benzimidazoles. Applied Organometal. Chem. 2025, 39, e70445.
48. Zhang, Jian; Tang, Zhe; Weng, Guang-Ju; Lu, Jian-Mei*; Shao, Li-Xiong* One-pot, three-component synthesis of 4H-pyrans catalyzed by one-dimensional zinc-organic frameworks. J. Mol. Strucct. 2025, 1343, 142822.
47. Yu, Yi-Han; He, Jia-Lu; Wang, Hai-Lan; Weng, Guang-Ju; Wu, Jia-Qi; Lu, Jian-Mei*; Shao, Li-Xiong* 2D cerium-organic frameworks as an efficient heterogeneous catalyst for the synthesis of 1,4-dihydropyridines via Hantzsch reaction. Chem. Asian J. 2025, 20, e202400977.
46. Wang, Chao; Zhou, Quan; Liang, Ke-Jiang; Bo, Xiao-Xu*; Ding, Yi-Hong*; Shao, Li-Xiong* Double direct C-H bond arylation of thiophenes with aryl chlorides catalyzed by N-heterocyclic carbene-PdCl2-1-methylimidazole complex. J. Org. Chem. 2024, 89, 12533-12539.
45. Weng, Guang-Ju; Cheng, Kang-Min; Wu, Jia-Qi; Li, Wei*; Lu, Jian-Mei*; Shao, Li-Xiong* Construction of a terbium-based metal-organic framework for specific detection of MnO4- in aqueous media. New J. Chem. 2024, 48, 3588-3593.
44. 邵黎雄;陆建梅*;姜雪峰:有机化学实验“线上线下”混合的探索与实践。化学教育(中英文) 2023,44(20),54-59。
43. 邵黎雄 主编;陈锡安、夏远志 副主编:有机化学课程思政案例。化学工业出版社,2023年,ISBN:978-7-122-44218-5。
42. Wu, Jia-Qi; Wu, Xin-Yuan; Lu, Jian-Mei*; Shi, Qian*; Shao, Li-Xiong* Highly active La(III)-based metal-organic framework as a heterogeneous Lewis acid catalyst for Friedel-Crafts alkylation. Chem. Eur. J. 2022, 28, e202202441.
41. Wu, Jia-Qi; Ma, Xin-Yue; Liang, Cheng-Long; Lu, Jian-Mei*; Shi, Qian*; Shao, Li-Xiong* Design of An antenna effect Eu(III)-based metal-organic framework for highly selective sensing of Fe3+. Dalton Trans. 2022, 51, 2890-2897.
40. Zhang, Zhi-Mao; Xu, Yu-Ting; Shao, Li-Xiong* Synthesis of N-heterocyclic carbene-Pd(II)-5-phenyloxazole complexes and initial studies of their catalytic activity toward the Buchwald-Hartwig amination of aryl chlorides. J. Organometal. Chem. 2021, 940, 121683.
39. 邵黎雄;陆建梅*;姜雪峰:味觉化学之苦味化学。化学教育(中英文) 2020,41(17),7-14。
38. 邵黎雄;陆建梅*;姜雪峰:味觉化学之酸味化学。化学教育(中英文) 2020,41(13),1-5。
37. 邵黎雄;余小春;陆建梅*;姜雪峰:氮杂环卡宾-钯配合物催化偶联反应最新研究进展。化学教育(中英文) 2020,41(10),1-11。
36. Lu, Jian-Mei; Shao, Li-Xiong Benzothiopyrylium salts. Science of Synthesis Knowledge Updates. 2020, 3, 341-406.
35. Bao, Zhen; Zhou, Zhi-Yuan; Mao, Ye-Ting; Shao, Li-Xiong* N-Heterocyclic carbene-Pd(II)-1-methylimidazole complex-catalyzed Suzuki-Miyaura coupling of 2-chloro-4-aminoquinazolines with arylboronic acids. Tetrahedron 2020, 76, 131548.
34. 邵黎雄;陆建梅*;姜雪峰:硒,人类不可或缺的元素。自然杂志 2019,41(6),453-459。
33. Shao, Li-Xiong; Li, Yi-Ming; Lu, Jian-Mei*; Jiang, Xue-Feng* Recent progress in selenium-catalyzed organic reactions. Org. Chem. Front. 2019, 6, 2999-3041.
32. Yin, Shun-Chao; Zhou, Quan; He, Qian-Wei; Li, Shu-Wan; Qian, Peng-Cheng*; Shao, Li-Xiong* N-Heterocyclic carbene-Pd(II)-1-methylimidazole complex catalyzed C-H bond arylation of (benzo)thiophenes with aryl chlorides. Tetrahedron 2017, 73, 427-431.
31. Liu, Qing-Xian; He, Bang-Yue; Qian, Peng-Cheng*; Shao, Li-Xiong* N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed direct C-H bond arylation of imidazo[1,2-a]pyridines with aryl chlorides. Org. Biomol. Chem. 2017, 15, 1151-1154.
30. Ji, Ya-Yun; Zhang, Yu; Hu, Yuan-Yuan; Shao, Li-Xiong* N-Heterocyclic carbene-Pd(II)-1-methylimidazole complex catalyzed C-H bond benzylation of (benzo)oxazoles with benzyl chlorides. Tetrahedron 2015, 71, 6818-6823.
29. Yin, Hui-Ying; Lin, Xia-Li; Li, Shu-Wan; Shao, Li-Xiong* N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed a-arylation reactions of tetralones with aryl chlorides and further transformation of the products. Org. Biomol Chem. 2015, 12, 9012-9021.
28. Yin, Shun-Chao; Zhou, Quan; Zhao, Xiao-Yun; Shao, Li-Xiong* N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed direct C-H bond arylation of benzo[b]furans with aryl chlorides. J. Org. Chem. 2015, 80, 8916-8921.
27. Ji, Ya-Yun; Lu, Li-Li#; Shi, Yu-Chun#; Shao, Li-Xiong* Direct C-H bond arylation of fluorenes with aryl chlorides catalyzed by N-heterocyclic carbene-palladium(II)-methylimidazole complex and further transformation of the products in a one-pot procedure. Org. Biomol. Chem. 2014, 12, 8488-8498. (#These two authors contributed equally.)
26. Gu, Zheng-Song; Chen, Wen-Xin; Shao, Li-Xiong* N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex-catalyzed direct C-H bond arylation of (benz)imidazoles with aryl chlorides. J. Org. Chem. 2014, 79, 5806-5811.
25. Shen, Xiao-Bao; Zhang, Yun; Chen, Wen-Xin; Xiao, Zheng-Kang; Hu, Ting-Ting; Shao, Li-Xiong* Direct C-H bond arylation of (benzo)oxazoles with aryl chlorides catalyzed by N-heterocyclic carbene-palladium(II)-1-methylimidazole complex. Org. Lett. 2014, 16, 1984-1987.
24. Chen, Wen-Xin; Zhang, Cai-Yun; Shao, Li-Xiong* Base-promoted N-alkylation using formamides as the N-sources in neat water. Tetrahedron 2014, 77, 880-885.
23. Yin, Hui-Ying; Liu, Meng-Yuan; Shao, Li-Xiong* Two-component, three-molecule reactions between 2,3-dihydroinden-1-ones and aryl chlorides catalyzed by N-heterocyclic carbene-palladium(II)-1-methylimidazole complex. Org. Lett. 2013, 15, 6042-6045.
22. Wang, Zhan-Yong; Ma, Qin-Na; Li, Ren-Hao; Shao, Li-Xiong* Palladium-catalyzed Suzuki-Miyaura coupling of aryl sulfamates with arylboronic acids. Org. Biomol. Chem. 2013, 11, 7899-7906.
21. Xiao, Zheng-Kang; Yin, Hui-Ying; Shao, Li-Xiong* N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed a-arylation of oxindoles with aryl chlorides and aerobic oxidation of the products in a one-pot procedure. Org. Lett. 2013, 15, 1254-1257.
20. Lu, Jian-Mei; Shao, Li-Xiong; Shi, Min Chemical Transformation of Vinylidenecyclopropanes. Springer, 2012, ISBN 978-3-642-27572-2.
19. Shi, Min*; Lu, Jian-Mei, Wei, Yin; Shao, Li-Xiong* Rapid generation of molecular complexity in the Lewis or Brønsted acid-mediated reactions of methylenecyclopropanes. Acc. Chem. Res. 2012, 45, 641-652.
18. Wang, Zhan-Yong; Chen, Gao-Qi; Shao, Li-Xiong* N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed Suzuki-Miyaura coupling of aryl sulfonates with arylboronic acids. J. Org. Chem. 2012, 77, 6608-6614.
17. Chen, Wen-Xin; Shao, Li-Xiong* N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed amination between aryl chlorides and amides. J. Org. Chem. 2012, 77, 9236-9239.
16. Gao, Ting-Ting; Jin, Ai-Ping; Shao, Li-Xiong* N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed Mizoroki-Heck reaction of aryl chlorides with styrenes. Beilstein J. Org. Chem. 2012, 8, 1916-1919.
15. Zhu, Lei; Ye, Yue-Mei; Shao, Li-Xiong* Well-defined NHC-Pd(II)-Im (NHC = N-heterocyclic carbene; Im = 1-methylimidazole) complex catalyzed C-N coupling of primary amines with aryl chlorides. Tetrahedron 2012, 68, 2414-2420.
14. Xiao, Zheng-Kang; Shao, Li-Xiong* NHC-Pd(II)-Im (NHC = N-heterocyclic carbene; Im = 1-methylimidazole) complex catalyzed a-arylation of ketones with aryl chlorides. Synthesis 2012, 44, 711-716.
13. Tang, Yi-Qiang; Chu, Chun-Yan; Zhu, Lei; Qian, Bin; Shao, Li-Xiong* N-Heterocyclic carbene-Pd(II) complex derived from proline for the Mizoroki-Heck reaction in water. Tetrahedron 2011, 67, 9479-9483.
12. Zhu, Lei; Gao, Ting-Ting; Shao, Li-Xiong* Well-defined NHC-Pd(II)-Im (NHC = N-heterocyclic carbene; Im = 1-methylimidazole) complexes catalyzed amination of aryl chlorides. Tetrahedron 2011, 67, 5150-5155.
11. Zhou, Xia-Xia; Shao, Li-Xiong* N-Heterocyclic carbine/Pd(II)/1-methylimidazole complex catalyzed Suzuki-Miyaura coupling reaction of aryl chlorides in water. Synthesis 2011, 3138-3142.
10. Tang, Yi-Qiang; Lu, Jian-Mei; Shao, Li-Xiong* NHC-Pd(II)-Im (NHC = N-heterocyclic carbene; Im = 1-methylimidazole) complexes as efficient catalysts for Suzuki-Miyaura coupling reactions of aryl chlorides at room temperature. J. Organomet. Chem. 2011, 696, 3741-3744.
9. Shen, Xiao-Bao; Gao, Ting-Ting; Lu, Jian-Mei; Shao, Li-Xiong* Imidazole-coordinated monodentate NHC-Pd(II) complex derived from proline and its application towards the coupling reaction of arylboronic acids with carboxylic acid anhydrides in water at room temperature. Appl. Organometal. Chem. 2011, 25, 497-501.
8. Tang, Yi-Qiang; Lv, Huan; Lu, Jian-Mei; Shao, Li-Xiong* Palladium(II)-N-heterocyclic carbene complex derived from proline towards Suzuki-Miyaura coupling reaction in water at room temperature. J. Organomet. Chem. 2011, 696, 2576-2579.
7. Tang, Yi-Qiang; Lv, Huan; He, Xiao-Na; Lu, Jian-Mei; Shao, Li-Xiong* N-Heterocyclic carbene-rhodium(I) complexes derived from proline for the 1,4-conjugate addition of arylboronic acids to enones in neat water. Catal. Lett. 2011, 141, 705-708.
6. Wang, Bin-Bin; Ye, Yue-Mei; Chen, Jun-Jun; Zhou, Xia-Xia; Lu, Jian-Mei; Shao, Li-Xiong* 2,2’-Diamino-6,6’-dimethylbiphenyl as an efficient ligand in the CuI-catalyzed Sonogashira reaction of aryl iodides and bromides with terminal alkynes. Bull. Chem. Soc. Jpn. 2011, 84, 526-530.
5. Shi, Min*; Shao, Li-Xiong; Lu, Jian-Mei; Wei, Yin; Mizuno, Kazuhiko*; Maeda, Hajime Chemistry of vinylidenecyclopropanes. Chem. Rev. 2010, 110, 5883-5913.
4. Lu, Jian-Mei; Ma, Hui; Li, Sha-Sha; Ma, Dan; Shao, Li-Xiong* 2,2’-Diamino-6,6’-dimethylbiphenyl as an efficient ligand in the palladium-catalyzed Suzuki-Miyaura and Mizoroki-Heck reactions. Tetrahedron 2010, 66, 5185-5189.
3. Tang, Yi-Qiang; Lu, Jian-Mei; Wang, Xiu-Ren; Shao, Li-Xiong* Palladium(II)-N-heterocyclic carbene complexes derived from proline: synthesis and characterization. Tetrahedron 2010, 66, 7970-7974.
2. Qi, Ming-Hui; Shao, Li-Xiong*; Shi, Min* PdCl2-promoted reactions of diaryl-substituted methylenecyclopropanes. Dalton Trans. 2010, 39, 8829-8834.
1. Zhu, Zhi-Bin; Shao, Li-Xiong*; Shi, Min* Brønsted acid or solid acid catalyzed aza-Diels-Alder reactions of methylenecyclopropanes with ethyl (arylimino)acetates. Eur. J. Org. Chem. 2009, 2576-2580.
主要项目
5. 高效氮杂环卡宾-钯催化剂的开发(已结题)。
4. 高价碘与环氧乙烷类化合物的微通道制备技术开发(已结题)。
3. 浙江省自然科学基金(No.: LY12B02012) (已结题)。
2. 国家自然科学基金(No.: 20702013) (已结题)。
1. 浙江省高等学校优秀青年教师资助计划项目(已结题)。
获奖及荣誉
24. 2024年度温州大学优秀班主任。
23. 温州大学第四届教师教学创新大赛实验技能专项赛二等奖。
22. 2023年杏吧视频
师德先锋。
21. 温州大学第十一届华峰品德奖。
20. 温州大学2022/2023学年优秀基层教学组织(有机化学教学团队)。
19. 2021年度温州大学优秀教师。
18. 2016年浙江省高校优秀共产党员。
17. 温州大学2014年度优秀共产党员;
16. 2014年浙江省教学成果二等奖(第五完成人);
15. 2013年上海市自然科学一等奖(第三完成人);
14. 2013年杏吧视频
“华峰院长奖”;
13. 2013年校第二届研究生“我心目中的好导师”;
12. 2013年杏吧视频
“我最尊敬的老师”;
11. 2013年作为团队成员获得温州大学校长特别奖;
10. 2013年全国“挑战杯”大学生课外学术科技作品竞赛累进创新银奖(第一指导教师);
9. 2012年入选温州大学“学生科技创新十佳指导教师”;
8. 2012年杏吧视频
“我最尊敬的老师”;
7. 2012年温州大学教学成果奖一等奖(第五完成人);
6. 2011年温州大学校长特别奖;
5. 2011年全国“挑战杯”大学生课外学术科技作品竞赛二等奖(第一指导教师);
4. 2011年浙江省“挑战杯”大学生课外学术科技作品竞赛特等奖(第一指导教师);
3. 2011年温州大学创先争优“教书育人模范”;
2. 2010年入选温州市551人才第二层次;
1. 2008年入选温州市551人才第三层次。