讲题：金属簇合物的研究前沿及应用

主讲：厦门大学 龙腊生 教授 (国家杰出青年基金获得者)

时间：2016年12月5日（周一）上午9点

地点：化材楼11B-208会议室

龙腊生教授简介

厦门大学化学化工学院化学系、固体表面物理化学国家重点实验室，教授，博士生导师。闽江学者特聘教授，国家杰出青年基金获得者。福建省科技创新领军人才。中国晶体协会理事，无机化学学报编委。曾任Cryst. Growth Des.专题编辑 (Topic Editor， 2012-2015年)。曾获全国优秀博士学位论文指导教师奖（2011）和卢嘉锡优秀导师奖（2012）。

主要研究方向： 1）高核稀土及稀土-过渡金属簇的设计合成与磁热效应； 2）介电、铁电及导电材料设计与合成。

迄今为止，在包括Acc. Chem. Res., Proc. Natl. Acad. Sci. USA, J. Am. Chem. Soc.,Angew. Chem. Int. Ed., Chem. Eur. J.,Chem. Commun., Chem. Mater.等杂志上发表研究论文100余篇。相关研究结果被美国《化学工程新闻》 (C&EN 2007, issue of May 21，p9；C&EN 2007, issue of October 29，p30.)，Nature (2007, 447, 1035) ，Nature Nontechnology (2007, 2, 388-389)，Chemical Science (2009, May 14)，美国化学会Heart Cut（2002, October 14，www.chemistry.org）以及著名网站Physorg.com，physics inventions等选为研究亮点进行了报道或专门评价。在磁热效应方面的研究工作被收录在《Quantum Molecular Magnets》专辑中。

2007年来代表性研究论文

1)     D. P. Liu, X. P. Lin, H. Zhang, X. Y. Zheng, G. L. Zhuang*, X. J. Kong,* L. S. Long,* L. S. Zheng, Magnetic Properties of a Single-Molecule Lanthanide-Transition-Metal Compound Containing 52 Gadolinium and 56 Nickel Atoms, Angew. Chem. Int. Ed.2016, 55, 4532-4536.

2)     J. B. Peng, X. J. Kong,* Q. C. Zhang, M. Orendá?, J. Prokleška, Y. P. Ren, L. S. Long,* Z. P. Zheng, L. S. Zheng, Beauty, Symmetry, and Magnetocaloric Effect – Four-shell Keplerates with 104 Lanthanide Atoms, J. Am. Chem. Soc.2014, 136, 17938.

3)     Q. C. Zhang, F. T. Wu, H. M. Hao, H. Xu, H. X. Zhao,* L. S. Long,* R. B. Huang, L. S. Zheng, Modulating the Rotation of a Molecular Rotor through Hydrogen-Bonding Interactions between the Rotator and Stator, Angew. Chem. Int. Ed.2013, 52, 12602 –12605.

4)     J. B. Peng, Q. C. Zhang, Y. Z. Zheng, X. J. Kong,* Y. P. Ren,L. S. Long,* R. B. Huang, L. S. Zheng, Z. P. Zheng, High–Nuclearity 3d–4f Cluster–Based Chains as Enhanced Magnetic Coolers and Molecular Magnets, J. Am. Chem. Soc.2012, 134, 3314−3317.

5)   J. B. Peng, Y. P. Ren, X. J. Kong,* L. S. Long,* R. B. Huang, L. S. Zheng, Z. P. Zheng, A 48-Metal Cluster Exhibiting a Giant Magnetocaloric Effect, Angew. Chem. Int. Ed.2011, 50, 10649–10652.

6)   B. Zhou, A. Kobayashi,* H. B. Cui, L. S. Long, H. Fujimori, H. Kobayashi,* Anomalous Dielectric Behavior and Thermal Motion of Water Molecules Confined in Channels of Porous Coordination Polymer Crystals, J. Am. Chem. Soc.2011, 133, 5736–5739.

7)   H. X. Zhao, X. J. Kong, H. Li, Y. C. Jin, L. S. Long,* X. C. Zeng,* R. B. Huang, and L. S. Zheng, Transition from One-dimensional Water to Ferroelectric Ice within a Supramolecular Architecture, Proc. Natl. Acad. Sci. USA, 2011, 108, 3481-3486.

8)   X. J. Kong, L. S. Long,* Z. P. Zheng,* R. B. Huang, L. S. Zheng, Keeping the Ball Rolling-Fullerene-like Molecular Clusters, Acc. Chem. Res.2010, 43, 201-209.

9)   X. J. Kong, Y. L. Wu, L. S. Long,* L. S. Zheng, Z. P. Zheng,* A Chiral 60-Metal Sodalite Cage Featuring 24 Vertex-sharing [Er₄(μ₃-OH)₄] Cubanes, J. Am. Chem. Soc.2009, 131, 6918–6919.

10) H. B. Cui, B. Zhou, L. S. Long, Y. Okano, H. Kobayashi,* A. Kobayashi, Porous Coordination Polymer Crystal Containing One-dimensional Water Chains Exhibiting Guest-Induced Lattice Distortion and Dielectric Anomaly, Angew. Chem. Int. Ed.2008, 47, 3376–3380.

11) X. J. Kong, Y. P. Ren, W. X. Chen, L. S. Long,* Z. P. Zheng,* R. B. Huang, L. S. Zheng, A four-shell, nesting doll-like 3d-4f cluster containing 108 metal ions, Angew. Chem. Int. Ed.2008, 47, 2398–2401.

12) S. T. Wu, Y. R. Wu, Q. Q. Kang, H. Zhang, L. S. Long?,* Z. P. Zheng?,* R. B. Huang, L. S. Zheng, Chiral Symmetry Breaking by Chemically Manipulating Statistical Fluctuation in Crystallization, Angew. Chem. Int. Ed.2007, 46, 8475–8479.

13) X. J. Kong, Y. P. Ren, L. S. Long,* Z. P. Zheng,* R. B. Huang, L. S. Zheng, A Keplerate magnetic cluster featuring an icosidodecahedron of Ni(II) ions encapsulating a dodecahedron of La(III) ions. J. Am. Chem. Soc.2007, 129, 7016–7017.